Not the way I would do it it, but probably works to a certain extent. If he had my equipment he could do it more professionally.
Alternatively as I said , with engine warm it is under pressure already as long as the pressure cap is screwed down so when you open the bleed screws then the air will come out.
Another very important thing to consider is why you have a pressurised cooling system in the first place. It allows the engine to run at a slightly higher temperature where it is more efficient whilst still keeping a safety reserve.
Note, it is not the high temperature which damages an engine, it is when that water/coolant boils and becomes a gas, at which point any localised hot spots can rapidly exceed the normal boiling point of water, it is why pressure cookers work.
Remember for every lb of pressure above the water in a pressurised cooling system it means the water boils at 1.5 degrees Centigrade higher than the normal boiling point of water at sea level of 100 Degrees Centigrade, so a 10lb rad cap will allow the water to reach 115 Degrees Centigrade before boiling and causing damage, so with your coolant system the rad. cap which is almost 1.Bar pressure it means that the water could be 122.5 Degrees Centigrade without causing damage. However once you open that rad cap the water will instantly boil causing damage, you mentioned a temp reading of just roughly 98 Degrees Centigrade from your OBD scanner so if that is correct it would mean the water /coolant if you opened the pressure cap would be just about to turn to a gas! So not a good idea to remove the rad cap on a hot engine.
Many times in the past I have seen a motorist drive in to the forecourt with a hot engine release the rad cap and the next thing a jet of steam and water shoot out as he jump away dropping the rad cap, what often then happens is the idiot grabs the watering can and puts cold water into his hot engine with a very good chance of cracking the aluminium cylinder head.