The calipers that stick most often are the rear ones. If they're sticking, you will feel that the handbrake is floppy (without any resistance).. or that there is a little resistance but the rear discs feel really hot even after a half a kilometer.
I had smoke coming off my pads one time.. so don't test it by sticking your finger on the disc... it'll burn your hand off... just touch the caliper near to the pad and you will get the idea. If one disc is much hotter than the other one, it will prove that something is wrong.. but otherwise rear discs and calipers should stay quite cool. If you can feel heat on your face and smell burning then it's too hot.
Rebuilding the calipers is possible... but you need to dismantle the calipers and fit a repair kit. These cost about €20 from memory, whereas a refurbished (like new) caliper costs about €50 if you search.. so it might be easier to just replace the whole caliper. It'll last another 5 years without any trouble.
But before you buy anything, also remove the sliding pins (front and rear) and check that they move freely and "loose" in the caliper. If they're sticky, take them out, degrease them (and the holes), smooth out any rust marks with sandpaper and then refit them using brake grease. If your pins are *very* rusty and look nasty.. then you can buy new brake pins (a pair for each caliper) for around €10. They come with new rubber bellows and grease.
While the caliper is out to check that ^ also make sure the pads are not sticking in the caliper. Remove them (they should drop out easily). If they're tight or jammed, then poke them out and use a file to remove any rust or bubbles from the back-plate, where i fits into the caliper slides. They should be a nice fit.. not rattling but not jammed tight either.
Change the pads if the backing plate is too deformed or corroded. Brembo pads fit well. Cheaper pads fit less well (I usually have to file them down a bit to get them comfortable in the caliper). Use copper grease around the lugs, so that they don't corrode straight away.
The caliper pad slides ("springs") used to be stainless steel but pads manufacturers are sending out mild steel ones now. If yours are all there (4 per caliper) and stainless steel, just clean them with your mate's toothbrush and some degreaser. If you have mild steel ones, or yours are bent/loose they will make the pad jam, so get new ones if they can't be saved using a wire brush etc. New pads come with new spring/slides.
If one front caliper is sticking but the caliper looks okay, then it could be a knackered brake hose (they start to fall apart internally and cause a blockage which acts like a valve). You'll need a new hose... but this is less likely. Look at the caliper hardware first.
Ralf S.