Not so fast. The system's operation is more complex than anything that's been posted yet.
I've attached FIAT's own description - I warn you it's one of the more badly written (or translated) bits of eLearn but you'll see that the system gets information from both the temperature sensor on the evaporator and the OAT sensor in the passenger mirror (question for anyone who actually knows for sure: do pop versions
with AC have .the OAT sensor added as part of the package).
bgunn is correct in that the important thing is to prevent ice from blocking the evaporator and to do that, the sensor must measure the surface temperature of the evaporator (the air leaving the evaporator will always be a little warmer).
Have a look also at
this table; it might surprise you to know that air at freezing point can hold over half the water vapour of air at 10C so the potential for ice accumulation is there even on very cold days.
To prevent the screen from misting up, the temperature of the glass must be higher than the dewpoint of the air in the cabin. So to get rid of it, you either need to raise the temperature of the glass or lower the dewpoint of the air.
On soggy mild winter days when temps are around 10C, the AC is very effective in demisting because it removes moisture from the air, reducing the dewpoint. When the temps drop to freezing, the dewpoint of the ambient air outside will be much lower than the dewpoint of the air in the cabin, which is why opening the windows to clear the screen works better on colder days.
Another way to stop the screen from misting is to raise its surface temperature above the dewpoint of the cabin air, which is why blowing hot air over it or using a heating element is also effective.
The air we breathe out is always 100% saturated, so if you stay in a stationary car with the windows up, the dewpoint of the cabin air rises & the windows steam up.