Another way to check which piston is nr1, is if you set everything on the timing marks (like alex explained), and then just checking which of the cam lobes is in the air. Both of the lobes MUST be pointing upward, it then means that the cylinder is making compression and should be firing. Check your ignition leads and adjust the distributor until it sparks, or use a spare plug on the ignition lead of nr1 cylinder.. Btw, firing order is 1-3-4-2..
If everything is thightend and safe, you can start cranking the engine. Remember to adjust the distributor in small movements.
I've made the mitstake of switching nr1 piston with nr4, resulting in my eyebrows getting burned.
Hope it helps!!!