So it's an ECU ground BYPASS then (probably - wait till someone confirms, "2012" owners).
To protect the ECU in case of main ground failure. It probably goes to the ECU bracket/mount - car body.
You don't want to power starter motor for example, partially via ECU PCB traces.
Some ECUs should NOT have GND on the casing anyways, I mean, it's not connected internally (older versions like Grande/EVO are not grounded, there is like 100
kΩ resistance from the aluminium ECU case to the GND wires in the plugs/connectors).
Wire like that can also protect the ECU from the ignition system faults (or owner/mechanic mistakes), high voltage spikes etc.
Try Google Images (even reverse search your own car). Engine bay, Punto 2012 (1,2 8V).
Example. Wire goes somewhere behind the ECU and a bit down.