Conventional wisdom seems to be that you can take it down to the max skim measurements (the little dimples on the face of the head). After that you'll no longer have a "safe" engine. So you might want to look at an adjustable cam pulley, too.There are different thicknesses of HG available, also.
So many factors are important regarding detonation. Most obvious ones are fuelling and ignition timing. (Which is why I suggest an aftermarket ECU.) You also want to use the hardest plug you can without fouling (maybe an 8 or even 9 in the NGK range).
NA tuning to the limit is probably at least as expensive as going turbo.
"DIY flowbench" in Google throws up some stuff which might be of interest. Some good general ideas about porting here.
Thanks for that. Any idea what the approx thickness of the standard HG is once fitted? If it works out right is it possible to get rid of it and in its place either use a super thin metal HG or something like Hylomar Blue?
Just seems like a fairly cheap upgrade without too much extra messing if I'm gonna pull the head off to do some manifold to head porting work anyway.