Yes, in all likely hood it will fail the emissions test. Easy enough to fit the cat back on, or slip the MOT guy a fiver.
While I see "your tongue in cheek" I have to complain

slipping anybody anything to elude something, is ONLY something non Italian car drivers, chavs and boy racers would do.
Last thing I want to be hit by is any wheeled lethal weapon not fit for the road.
However, asking the tester if they can use their testers discretion and lift the idle revs a little to see if the emmisions become acceptable is perfectly valid and legal.
I've a long standing relationship with my local council MOT testing station over many years. Unlike my local Fiat garage who I take cakes etc. at Christmas my poor old MOT testers/station remain totally devoid of such good will gestures. We chat, we laugh, we even almost cry but neither side crosses that 'boundary'.
If they (as in council type MOT test stations who have nothing to gain from a fail) fail me then I KNOW it is a valid fail, and even if it was borderline then I take it as a job well done and a potential life saver.
Emissions are a real problem, especially with my Strada Abarth which would automatically fail current MOT standards for its year of manufacturer. Here the homolated figure % CO exceeds the MOT test level. I've managed to tune the car below the MOT level but doing so has it problems. Initially the MOT station (guys who knew/know their beans) understood that a twin sidedraft setup would be almost certain to fail the CO idle test. However they had the legal discretion to slightly lift the normal idle revs. If the CO level dropped below then that was OK. I had to go through this "discretion" loop many years ago. Since those days I carefully our 130TC to pass 'asis'
as presented tests.
Decent MOT stations are there to help you and not make money at your expense (beyond standard test fees).
Play clean, play safe and actually you will be better off, learn a shed load from the testers and be legal.