Yes if you plan to take the head off, its best to do a CC measurement to get a true C/R.. when i machined my heads i used a "burette" and a peice of clear acrylic plastic to measure the head chamber ML displacement. you can then measure the cyl bore, head gasket thickness and calculate the TDC volume. And by knowing the crank stroke, you can calculate a accurate C/R.
I don't have my notes in front of me, but if i recall, after shaving the head on mine, i settled around 9.4:1 CR. Any more, and things can get a bit spicy on pump gas.
When i rebuilt a 75 2.7 911 engine, its head geomerty and pistion shape did not like anything above 9.5:1 CR on our 91 octane gas. I had to add thicker base cyl shims to bring it down to around 9.3:1.. Just the way this particular engine was.