I agree, when it comes to problems then there are weird things that can fox even the most experienced air con engineer. But there are some very simple and safe tests you can do.
Not many people have the low and high side aircon pressure gauges and it's pretty dangerous if you get it wrong but air con is all about temperature and most people have a thermometer of some sorts. Manuals seem to go on about testing the temperature at the face vents but you could sit there for ages waiting for things to happen and a blocked cabin filter or poor air flow will still leave you scratching your head wondering where the problem is. It will depend on the ambient temperature and temperature in the car cabin too. In the meantime you're sweltering wondering when things are going to happen
Go for the more raw stuff of "is the aircon cooling properly?" because if that's not then you're wasting your time sitting in the cabin with that puzzled look on your face
At the aircon refill point there should be a huge difference in temperature within minutes of starting the air con at the two pipes there.
That's your low pressure/low temp and high pressure/high temp pipes right there. Outside temp is 18C today
Here's low side temp after 2min from start up, thermocouple directly on the low pressure/cold pipe
and high side temp after 2min, thermocouple directly on the high pressure/hot pipe
so it's already showing a difference of 34C
4 minutes after start up
low side temp
High side temp
So now there is a difference of 45C and we can't go much lower than 4 degrees without safety devices stopping the aircon compressor
So you have already worked out in minutes that your air con is cooling well. If you're not getting the cold air into the cabin then you know you have an air distribution fault like blocked cabin filter or blower or distribution flaps because you can see that 4C is available, you just have to get it circulating in the cabin
To find faults then you need to have a clear grasp of how the A/C works without getting into mind blowing detail and this explains it pretty well and, for once, the system diagram is very similar to the Stilo
http://www.mistermatic.co.uk/aircon/theory.htm