If you can get an impact gun in there, it'd work a treat.
Usually they can be undone reasonably easily with a normal socket and breaker bar, but yours look a bit rusty. The amount of rust is unusual, unless you live in a particularly salty area, or they've not been disturbed for a long time.
Most likely point of leak will be the water pump. Probably time to replace the timing belt and tensioner at the same time, as you have to remove the belt. Access is a bit tight, but otherwise all straightforward.