Does your Multipla have rear disc brakes? (Some did for a while, and then they reverted to drums like the earlier models for some reason). A disc brake gets hot very quickly. If the handbrake is applied when the discs are hot, as they cool (and contract) the brake pads are not pressed so tightly against the disc. This used to be a real problem to the drivers of Citroens, esp the BX like I had, where the handbrake worked on the front discs which get much hotter. Ours frequently rolled away!
Our Multipla, with rear drum brakes, has occasionally rolled too: once into the garage door, resulting in the insurers paying for a new bonnet and new garage door. Always park it in gear now, 'just in case'
Pete